Lesson 6: What is a rate constant

What is a rate constant?

 

I mentioned earlier that reactions occur at different rates. An explosion from setting hydrogen on fire may last only a couple of seconds. The reactions involved in baking a cake might take a few minutes to a few hours. The chemistry that rusts your bike can take months or years. In our example above, the decay of carbon-14 takes thousands of years.

A rate constant tells you how fast a reaction goes. We might expect our explosion to have a very large rate constant, while carbon-14 might have a very small one. But how do we find out what this rate constant is?

A neat trick that scientists often use is to linearlize data. Remember that exponential decay from before? If we take the natural log of both sides with can get a new equation that looks like this:

linearlizedequation.png

If you look closely you should be able to see that plotting ln[C-14]t on the y-axis and t on the x-axis should give a straight line with an intercept of ln[C-14] at time 0 and a slope of k. That allows us to find our rate constant! But first let's program this linear data in python. Remember our data file is called carbondecay.csv

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You should be getting a graph that looks like the one below. We will talk about how to calculate the rate constant from this graph in the next section.

 

foo2.png